Volume 390
Main Index

Issue 1, Pages 1-126 (26 June 1990)

Cr(CO)5(CNCN), a complex in which the coordinated CN group of isocyanogen binds and vibrates like a CO ligand Pages c1-c5 G. C. Schoemaker, D. J. Stufkens, S. J. Goede, T. van der Does and, F. Bickelhaupt

Author index Page c20

Indium monohalide insertion reactions into metal—metal bonds. Crystal structure of [InCl(THF){Mo(CO)3(η-C5H5)}2] Pages c10-c15 L. M. Clarkson, N. C. Norman, L. J. Farrugia

Asymmetric synthesis of chiral amines via nucleophilic addition to ferrocenylalkyl substituted imines Pages c6-c9 Dorothy M. David, Leon A. P. Kane-Maguire, Stephen G. Pyne

Distinct reaction pathways for some classical and nonclassical transition metal dihydrides Pages c16-c19 Claudio Bianchini, Maurizio Peruzzini, Fabrizio Zanobini

Modifizierte Isopinocampheyldibromborane; selektive Katalysatoren für asymmetrische Diels-Alder-rekationen Pages 1-6 Gerhard Bir, Dieter Kaufmann

Reaction of phenyl(trimethylsilyl)silylene with chloromethanes; Insertion into the C---Cl bond and abstraction of chlorine and HCl Pages 7-18 Kunio Oka, Ren Nakao

Synthesis of triorganostannate esters of dicarboxylic acids. Crystal structure of bis(dicyclohexylammonium) trisoxalatotetrakis(tri-n-butylstannate) · 2 ethanol Pages 19-28 Seik Weng Ng, V. G. Kumar Das, M. B. Hossain, F. Goerlitz and, Dick van der Helm

The crystal and molecular structure of chloro-p-ethoxyphenyl-2-(2-pyridyl)phenyltelluronium(IV) trichloromercurate(II), a novel telluronium salt Pages 29-34 Tarlok S. Lobana, Shaaban A. Mbogo, William R. McWhinnie, Wyona C. Patalinghug and, Allan H. White

Dicyclopentadienylsamarium complexes with t-butyl substituents in the ring. Crystal and molecular structures of the solvate (η5-C5H3Bu2t)2Sm · OC4H8 and homoleptic ate complex [NaSm(η5:η2-C5H4But)3 · OC4H8]n Pages 35-44 V. K. Bel'sky, Yu. K. Gunko, B. M. Bulychev, A. I. Sizov, G. L. Soloveichik

Metallorganische verbindungen der lanthanoide : LVI. Synthese und röntgenstrukturanalyse von [Li(THF)4][(C5H5)2Lu(NPh2)2] Pages 45-52 Herbert Schumann, Eftimios Palamidis, Jörg Loebel

Metallacyclen des zirkonocens Pages 53-60 Helmut G. Alt, Christine E. Denner

Matrix photochemistry of the complexes (CO)5M = C(OMe)Ph (M = Cr, W) having close-lying reactive MLCT and LF states Pages 61-71 Peter C. Servaas, Derk J. Stufkens, Ad Oskam

Synthesis of new ferrocenyl amine sulfide and selenide complexes of group 10 metals and their catalytic activities toward selective hydrogenation, isomerization, and asymmetric Grignard cross-coupling reactions Pages 73-90 Ahmad A. Naiini, Chung-Kung Lai, Donald L. Ward, Carl H. BrubakerJr.

Kinetics and mechanism of the addition of methoxide ion to the π-hydrocarbon ligands in [HOs3(η2-CH=CH2)(CO)10] and [CpFe(CO)2(η2-CH2=CH2)]PF6 Pages 91-95 Tahany Ghazy, Leon A. P. Kane-Maguire, Kim Do

Reductive carbonylation of cobalt(II) salts containing weakly-coordinating anions in the presence of diphosphine ligands Pages 97-104 Alessandro Del Zotto, Pierluigi Rigo

Hex-1-ene hydroformylation catalyzed by Rh(acac){P(OPh)3}2 modified with amines, formation of reactive HRh(CO){P(OPh)3}3 and unreactive Rh4(CO)8{P(OPh)3}4 species Pages 105-111 A. M. Trzeciak

Crystal and molecular structure of 2,3-η2-(1,4-dimethoxybut-2-yne)bis(tricyclohexylphosphane)nickel(0), (Cy3P)2Ni(MeOCH2C---CCH2OMe); influence of phosphane ligands on acetylene complexation in nickel(0) complexes Pages 113-120 U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. V. Polyakov, A. I. Yanovsky and, Yu. T. Struchkov

Carbon-carbon bond formation upon ligand displacement from bis(chloromethyl)(1,5-cyclooctadiene)platinum(II) with tricyclohexylphosphine. X-ray structure of trans-di-μ-chlorobis(2-tricyclohexylphosphonioethyl)-bis(tricyclohexylphosphine)diplatinum(II) bis(hexafluorophosphate) Pages 121-126 Robert McCrindle, George Ferguson, Gilles J. Arsenault, Mark J. Hampden-Smith, Alan J. McAlees, Barbara L. Ruhl

Issue 2, Pages 127-274 (3 July 1990)

Synthesis and molecular structure of [η5-C5H5Mo(CO)2]2(μ,η2-Sb2). Formation of an Sb=Sb double bond from metallic antimony Pages c36-c38 James R. Harper, Arnold L. Rheingold

Bindungscharakteristik der H2-koordinierenden Fragmente W(CO)3(PR3)2. Aussergewöhnliche optische und elektrochemische Eigenschaften zweikerniger Pyrazinkomplexe Pages c45-c49 Wolfgang Bruns, Wolfgang Kaim

Reaction of alkenyl carbonyl ruthenium(II) complexes with t-butyl isocyanide. Synthesis of η1-acylruthenium(II) complexes by intramolecular CO insertion Pages c57-c60 Julio Montoya, Amelia Santos, Antonio M. Echavarren, Josep Ros

Photochemical generation of pyridine- and polypyridine-Co(I) complexes by visible light irradiation of [Co(bpy)3](BPh4)2 and [Co(py)6](BPh4)2 Pages c61-c63 Paolo Biagini, Tiziana Funaioli, Alberto Juris, Giuseppe Fachinetti

On the stereochemistry of chiral (η5-C9H7)Rh(diphosphine) complexes Pages c64-c68 Franco Morandini, Giambattista Consiglio

Electrogeneration of the molybdenum-molybdenum double bond from thiolate-bridged dinuclear precursors: carbon monoxide catalysed isomerisation about the Mo=Mo bond Pages c39-c44 Christine Le Floc'h, François Y. Pétillon, Christopher J. Pickett, Jean Talarmin

Synthesis and structure of heterometallic cluster complexes. Reaction of imido complex LWRu2(CO)8(μ-H)(μ3-NPh), L = CP and Cp, with the tungsten acetylide complex CpW(CO)3CCPh Pages c50-c56 Yun Chi, Ling-Kang Liu, Gottfried Huttner, Laszlo Zsolnai

The Elements : by John Emsley, Oxford University Press, Oxford, 1989, vii + 256 pages, £9.95 (soft cover). ISBN 0-19-855237-8 Pages c69-c70 Penny A. Chaloner

United States—Japan Seminar on Host—Guest Chemistry : edited by George W. Gokel and Kenji Koga, Advances in Inclusion Science, Vol. 6, Kluwer Academic Publishers, Dordrecht, 1989, viii + 279 pages, Dfl. 160, $88.00, £49.00. ISBN 0-7923-0262-1 Pages c70-c71 Penny A. Chaloner

Author index Page c72

1,1,2,2,9,9,10,10-Octamethyl-1,2,9,10- tetragerma[2.2]paracyclophane: the first [2.2]paracyclophane bridged by two Ge---Ge bonds Pages c27-c31 Akira Sekiguchi, Tetsuo Yatabe, Chizuko Kabuto, Hideki Sakurai

Charge relocation in cationic diene complexes: formation of an iminium-substituted allyl complex and its deprotonation to an enamine Pages c32-c35 Stephen A. Benyunes, Michael Green

Synthesis of organozinc enolates of N,N-disubstituted glycine esters. Crystal structure of [Et(t-Bu)Me]4 Pages c21-c26 Fred H. van der Steen, Jaap Boersma, Anthony L. Spek, Gerard van Koten

Comparison of the allylation reactions of aldehydes using allylstannanes with boron trifluoride etherate and boron trichloride Pages 127-138 Daniele Marton, Giuseppe Tagliavini, Michele Zordan, James L. Wardell

Isotope 13/12C effects on 119Sn nucleus shielding in ethynylstannanes Pages 139-152 E. Liepi, I. Birele, E. Lukevics, E. T. Bogoradovsky and, V. S. Zavgorodny

The crystal and molecular structure of the 20-electron alumohydride complex of bis(t-butylcyclopentadienyl)samarium {[(η5-C5H4But)2Sm(μ3-H)][(μ2-H)2AlH·OC4H8]}2 Pages 153-158 Yu. K. Gun'ko, B. M. Bulychev, A. I. Sizov, V. K. Bel'sky, G. L. Soloveichik

Acetylenkomplexe des titanocens als ausgangsverbindungen für fünfgliedrige titanacyclen Pages 159-169 Helmut G. Alt, Georg S. Herrmann

Note on the solvent dependence of the 1H-NMR coordination chemical shifts of tricarbonyl(η6-[8]paracyclophane) chromium. A caveat concerning its interpretation Pages 171-177 L. W. Jenneskens, W. H. de Wolf, F. Bickelhaupt

Friedel-Crafts acylation of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe(η5-C5H5) and crystal structure of (CO)2(NO)Cr(η5-C5H4)CH2(η5-C5H4)Fe(η5-C5H4)C(O)(η5-C5H4)Cr(CO)2(NO) Pages 179-192 Yu-Pin Wang, Jin-Mei Hwu, Sue-Lein Wang

Amidinato complexes of dicyclopentadienylmolybdenum. Synthesis and redox properties Pages 193-201 A. R. Dias, M. A. Queirós

Organometallic derivatives of diphosphinoamines, X2PN(R)PX2. Reactions with carbonyl derivatives of group 6 metals and iron pentacarbonyl. The crystal structures of [Mo(CO)4PhN(P(OPh)2)2] and [W(CO)4iPrN(PPh2)2] Pages 203-216 M. S. Balakrishna, T. K. Prakasha, S. S. Krishnamurthy, U. Siriwardane and, N. S. Hosmane

Spectroscopic investigation of chalcone-analogous ferrocenes ortho-substituted in the aromatic ring Pages 217-225 Ágnes G. Nagy, Pál Sohár

Cryptates from cryptands containing the ferrocene unit. Determination of equilibria stoicheiometries and stability constants Pages 227-235 C. Dennis Hall, Ian P. Danks, Nelson W. Sharpe

Diazadiene stabilized butadiene nickel(0) complexes: Synthesis, characterization and reaction with acetylene and carbon monoxide. Crystal structures of (dad)Ni-μ[σ1,4; η1–4-C4H4]Ni(dad) and (dad)Ni-μ[σ1,4; η1–4-C4H4]Ni(CO)2 Pages 237-250 Jacobus C. M. Sinnema, Gert H. B. Fendesak, Heindirk tom Dieck

Conformational effects in elementary steps in catalytic reactions. Oxidative addition of 3-bromoprop-1-ene to a palladium(II) metallacyclic complex Pages 251-255 Marta Catellani, Brian E. Mann

Synthesis and reactivity of palladium and platinum complexes containing the bis(diphenylphosphino) methanide ligand Pages 257-265 J. Forniés, R. Navarro, E. P. Urriolabeitia

Carbon monoxide insertion into trans-Pt(η1-C3H5)-(phosphine2)Cl complexes in benzene. Crystal structure of trans-[Pt(COCH2CH=CH2](PPh3)2Cl Pages 267-274 S. Dirè, R. Campostrini, G. Carturan, M. Calligaris and, G. Nardin

Issue 3, Pages 275-407 (10 July 1990)

Cyclopalladated 2-t-butyl-4,4-dimethyl-2-oxazoline: its preparation, and use in the functionalisation of a non-activated carbon-hydrogen bond Pages c84-c88 G. Balavoine, J. C. Clinet

Subject index Pages c95-c102

Unusually facile formation of a hexa-coordinated bisamine adduct by tetrakis(pentafluorophenyl)porphinatocobalt(II) and azaferrocene Pages c77-c80 Janusz Zakrzewski, Charles Giannotti

Synthesis of tris(trifluoromethyl)gallium and its adducts Pages c73-c76 M. A. Guerra, S. K. Mehrotra, D. W. Dyer, R. J. Lagow

Relative donor properties of sp3 and sp2 hybridised phosphorus atoms of the azadiphosphetine ring system RR′ (R = Et3C, R′ = But) towards transition metals Pages c89-c92 Robson Matos, Mohamed F. Meidine, John F. Nixon, Bernadette F. Trigo Passos, Edgar Niecke and, Detlef Barion

Author index Pages c93-c94

Asymmetric catalysis LVI. Enantioselective hydrosilylation of acetophenone with a rhodium/picolineoxazoline catalyst 1:1 Pages c81-c83 Henri Brunner, Paul Brandl

The reaction of benzotrihalides and benzal halides with magnesium. Synthetic and mechanistic studies Pages 275-292 E. C. Ashby, Dheya M. Al-Fekri

Monoorganomercury and diorganothallium derivatives of 2-thiobarbituric acid Pages 293-300 3aría S. García Tasende, Maria I. Suárez Gimeno, A. Sánchez, J. S. Casas, J. Sordo

Metallorganische verbindungen der lanthanoide LVIII. Zur struktur des dicyclopentadienyl-bis(trimethylsilyl)lutetat-anions Pages 301-308 Herbert Schumann, Juliana A. Meese-Marktscheffel, F. Ekkehardt Hahn

[(Me3Sn)2(Me3Sb)M(CN)6]∞ (M = Fe, Ru): Neuartige Organo-SnIV/SbV-Polymere von besonderer chemischer und thermischer stabilität Pages 309-315 Stefan Eller, Susan Dülsen, R. Dieter Fischer

Phosphiniden- und arsiniden-komplexe mit pentamethylcyclopentadienyl (Cp)-liganden am gruppe 15-element: Synthese und Cp-übertragung Pages 317-322 Peter Jutzi, Rainer Kroos

Reaktionen von (η2-formaldehyd)zirconocen-dimer mit heterokumulenen Pages 323-331 Gerhard Erker, Miguel Mena, Stefan Werner and, Carl Krüger

Synthesis, structure and properties of molybdenum(0) bialkyne complexes Pages 333-337 J. S. Lain, C. H. Cheng, C. Y. Cheng, S. L. Wang

Synthese und Charakterisierung von 1,3-dithia-2-boryl-[3]ferrocenophanen Pages 339-344 Dietmar Fest, Carl D. Habben

Substituted metal carbonyls XIII. Fe(CO)4(η1-dppf) [where DPPF = (Ph2PC5H4)2Fe]: a convenient building block for heterometallic complexes Pages 345-350 T. S. Andy Hor, Lai-Tee Phang

Reactions of tungsten and molybdenum propargyl complexes with Co2(CO)8, Co4(CO)12, and Cp2Mo2(CO)4. A crossover study of formation of (CO)3Cp(CO)2 Pages 351-360 George H. Young, Andrew Wojcicki

C---H bond activation by rhodium(I) and the mechanism of the olefin isomerization: new synthesis of β,γ-unsaturated ketones via η1- or η3-alkylallylrhodium(III) complexes by reductive elimination Pages 361-370 Chul-Ho Jun

Carbene derivatives of areneruthenium(II) complexes in one step from terminal alkynes Pages 371-378 Dominique Devanne, Pierre H. Dixneuf

Arene—ruthenaborane clusters I. Products of the reaction between [{(η6-C6Me6)2Ru2H4}RuB10H8(OEt)2] and carbon monoxide. Nuclear magnetic resonance studies and the crystal structure of [{(η6-C6Me6)2Ru2H2(CO)2}RuB10H8(OEt)2] Pages 379-387 M. Bown, J. M. Waters, X. L. R. Fontaine and, J. D. Kennedy

Efficient palladium-catalyzed synthesis of unsymmetrical donor—acceptor biaryls and polyaryls Pages 389-398 Christian Amatore, Anny Jutand, Serge Negri, Jean-Francois Fauvarque

Synthesis and decomposition of neutral palladium(IV) complexes containing fac-PdMe2R groups, including reductive elimination by η1-propenylpalladium(IV) complexes to form η3-propenylpalladium(II) species Pages 399-407 Peter K. Byers, Allan J. Canty, Peter R. Traill, Andrew A. Watson